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The determination of hydroxide and carbonate in concentrated sodium chloride solutions
Authors:WB Roolvink  M Bos
Institution:Akzo Zout Chemie Research, Analytical Department, HengeloThe Netherlands;Department of Chemical Technology, Twente University of Technology, EnschedeThe Netherlands
Abstract:A computer method for the determination of carbonate and hydroxide in concentrated (2.89 M) sodium chloride solutions is described. The method is based on multiparametric curve-fitting and can also be applied to salts of dibasic acids with unknown equilibrium constants. The systematic error is not more than 1%. The titration and calculation takes less than 20 min.
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