Synthesis of dehydroxy-trans-resorcylide by intramolecular alkylation of the protected cyanohydrin using a butadiene telomer as a building block |
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Authors: | Takashi Takaghashi Ichiro Minami Jiro Tsuji |
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Institution: | Tokyo Institute of Technology, Meguro, Tokyo 152, Japan |
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Abstract: | Dehydrroxy-trans-resorcylide () was synthesized by efficient intramolecular alkylation of the protected cyanohydrin. The butadiene telomer obtained by the palladium catalyzed reaction of butadiene with acetic acid was used as a suitable block of the carbocycle. |
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