The reactions of some 1,1,1-tribromo-alkyl systems with thiolate anions |
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| Authors: | Hark S. Baird Alireza Hoorfar Manjushri Mitra |
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| Affiliation: | Department of Organic Chemistry, University of Newcastle upon Tyne U.K. |
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| Abstract: | ![]()
Compounds containing a 1,1,1-tribromoethyl group are normally dehydrobrominated by reaction with sodium thiolates. If a 1,1,1-tribromobut-3-ene fragment is present cyclisation to a 2,2-dibromocyclopropylmethyl thioether or rearrangement are also observed. |
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