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Some new organotin(IV), aluminium(III)-μ-oxoisopropoxides and their benzoylacetone derivatives |
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| Authors: | Pramesh N. Kapoor Ajay K. Bhagi Ramesh N. Kapoor |
| Affiliation: | Department of Chemistry, University of Delhi, Delhi-110 007 India Department of Chemistry, University of Kurukshetra, Kurukshetra, Haryana India |
| Abstract: | The first organotin(IV), aluminium(III)-μ-oxoisoprovides of the type [R3SnOA](OiPr)2] (R = Me or Ph) have been made by heating of trimethyl- or triphenyl-tin acetate with aluminium isopropoxide. The reactions of these μ-oxoisopropoxides with benzoylacetone in 1:1 and 1:2 molar ratios yielded the compounds of the type [R3SnOAl(OiPr)(bzac)] and [R3SnOAl(bzac)2] (where R = Me or Ph and BZAC = deprotonated benzoylacetone), respectively. |
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