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Some new organotin(IV), aluminium(III)-μ-oxoisopropoxides and their benzoylacetone derivatives
Authors:Pramesh N Kapoor  Ajay K Bhagi  Ramesh N Kapoor
Institution:

Department of Chemistry, University of Delhi, Delhi-110 007 India

Department of Chemistry, University of Kurukshetra, Kurukshetra, Haryana India

Abstract:The first organotin(IV), aluminium(III)-μ-oxoisoprovides of the type R3SnOA](OiPr)2] (R = Me or Ph) have been made by heating of trimethyl- or triphenyl-tin acetate with aluminium isopropoxide. The reactions of these μ-oxoisopropoxides with benzoylacetone in 1:1 and 1:2 molar ratios yielded the compounds of the type R3SnOAl(OiPr)(bzac)] and R3SnOAl(bzac)2] (where R = Me or Ph and BZAC = deprotonated benzoylacetone), respectively.
Keywords:
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