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Reactions of tert-Butyl Tetraethylphosphorodiamidite with Acetic and Trifluoroacetic Acids
Authors:Sal'keeva  L K  Nurmagambetova  M T  Kurmanaliev  O Sh  Gazizov  T Kh
Institution:(1) Buketov Karaganda State University, Karaganda, Kazakhstan
Abstract:Reactions of tert-butyl tetraethylphosphorodiamidite with acetic and trifluoroacetic acids involve substitution of the amido group. This process was described by a scheme beginning with protonation of phosphorus and proved by modeling separate reaction stages. A probable scheme of the proposed reactions is described.
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