Mechanism and kinetics of crystallization of α-Fe in amorphous Fe81B13Si4C2 alloy

The non-isothermal crystallization of α-Fe from Fe₈₁B₁₃Si₄C₂ amorphous alloy was investigated. The kinetic parameters of crystallization process were determined by Kissinger and Kissinger–Akahira–Sunose (KAS) methods. It was established that the kinetic parameters of transformation do not change with the degree of crystallization in the range of 0.1–0.7. The kinetic model of the crystallization process was determined using the Malek's procedure. It was established that the primary crystallization α-Fe phase from amorphous alloy can be described by Šesták–Berggren autocatalytic model with kinetic triplet E_a = 349.4.0 kJ mol⁻¹, ln A = 50.76 and f(α) = α^0.72(1 − α)^1.02.