| 2,2'-联吡啶-3,3',6,6'-四羧酸过渡金属配合物的合成、结构及性质 |
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| 引用本文： | 邴颖颖,吴振廷,胡明.2,2'-联吡啶-3,3',6,6'-四羧酸过渡金属配合物的合成、结构及性质[J].无机化学学报,2015,31(10):2059-2064. |
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| 作者姓名： | 邴颖颖 吴振廷 胡明 |
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| 作者单位： | 内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021,内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021,内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021 |
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| 基金项目： | 国家自然科学基金(No.21361017),内蒙古自然科学基金(No.2012MS0214),内蒙古高等学校科学技术研究重点研究(No.NJZZ12012)资助项目。 |
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| 摘 要： | 以2,2'-联吡啶-3,3',6,6'-四羧酸(H4bptc)为配体,通过水热合成的方法与过渡金属盐合成了3个配合物,其分子式分别为Co2(H2bptc)2(H2O)4]·bpe·9H2O(1),Ni2(H2bptc)2(H2O)4]·bpe·9H2O(2),Ni2(H2bptc)2(H2O)4]·0.5bpp·7H2O(3)(bpe=1,2-二(4-吡啶基)乙烯,bpp=1,2-二(4-吡啶基)乙烷)。用红外光谱,X-射线单晶衍射对化合物的晶体结构进行了表征,并对这3个配合物的热稳定性进行了测试。化合物1~3为单核结构的配合物,它们均通过分子间氢键形成三维超分子结构。
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| 关 键 词： | 2 2'-联吡啶-3 3' 6 6'-四羧酸 配合物 合成 晶体结构 |
| 收稿时间： | 2015/3/18 0:00:00 |
| 修稿时间： | 7/9/2015 12:00:00 AM |
Syntheses, Crystal Structures and Properties of Three Transition Metal Coordination Compounds Based on 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid |
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| BING Ying-Ying,WU Zhen-Ting and HU Ming.Syntheses, Crystal Structures and Properties of Three Transition Metal Coordination Compounds Based on 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2015,31(10):2059-2064. |
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| Authors: | BING Ying-Ying WU Zhen-Ting and HU Ming |
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| Institution: | Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China,Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China and Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China |
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| Abstract: | Three transition metal complexes, namely, Co2(H2bptc)2(H2O)4]·bpe·9H2O (1), Ni2(H2bptc)2(H2O)4]·bpe·9H2O (2), Ni2(H2bptc)2(H2O)4]·0.5bpp·7H2O (3) (H4bptc=2,2'-bipyridine-3,3',6,6'-tetracarboxylic acid, bpe=1,2-di(4-pyridyl)ethylene, bpp=1,2-di(4-pyridyl) ethane) have been synthesized under hydrothermal conditions and structurally characterized by infrared spectra, thermogravimetric analyses and single crystal X-ray diffraction. Compounds 1~3 are the mononuclear units and extended further to generate the three-dimensional supramol-ecular architectures by strong hydrogen-bonding interactions, respectively. CCDC: 1054309, 1; 1054310, 2; 1054311, 3. |
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| Keywords: | 2 2'-bipyridine-3 3' 6 6'-tetracarboxylic acid coordination compound synthesis crystal structure |
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