Abstract: | The mechanism of coating formation from solutions of atactic polystyrene in xylene and carbon tetrachloride has been investigated. It has been established that, as the filler content increases, in coatings formed from polystyrene solutions containing an evaporating solvent the growth of the internal stresses and the thermophysical characteristics is characterized by similarity of slope, as distinct from the case of coatings obtained from systems containing a polymerizing solvent. It is shown that the nature of the solvent has an important effect on the character of the interaction at the polymer—filler interface and on the structure and properties of the coatings.Kucherenko Central Scientific-Research Institute of Structural Design. Institute of Physical Chemistry, AS USSR, Moscow. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 1127–1129, November–December, 1968. |