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Vinylsulfones versus alkylsulfones in the addition to chiral imines. Synthesis of N-(tert-butoxycarbonyl)-l-homophenylalanine |
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| Authors: | David Dí ez,Pilar Garcí a,Pilar Basabe,H.B. Broughton |
| Affiliation: | a Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain b Lilly, S.A., Avda. de la Industria 30, 28108 Alcobendas, Madrid |
| Abstract: | A study of the addition of vinylsulfones versus alkylsufones has been done, and applied to the synthesis of N-(tert-butoxycarbonyl)-l-homophenylalanine. |
| Keywords: | Alkyl and vinyl sulfones Aminoacids Chiral imines Hydride transfer |
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