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Transformation of thioacetals to cyclopropanes |
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| Authors: | Takeshi Takeda Koutaro Arai Hirohisa Shimokawa Akira Tsubouchi |
| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan |
| Abstract: | Cyclopropanes were obtained by the titanocene(II)-promoted reaction of thioacetals with vinyl pivalate. It was also found that vinycyclopropanes were produced by a similar treatment of thioacetals with the titanocene(II) species in the presence of 1,3-dienes. |
| Keywords: | Cyclopropanation Titanocene(II) reagent Thioacetals Vinyl pivalate 1 3-Dienes |
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