Highly efficient Beckmann rearrangement and dehydration of oximes |
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| Authors: | Dongmei Li |
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| Institution: | Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
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| Abstract: | Under mild conditions, Beckmann rearrangement of a variety of ketoximes could proceed in the presence of chlorosulfonic acid using toluene as a solvent with excellent conversion and selectivity. This procedure could also be applied in the dehydration of aldoximes for obtaining the corresponding nitriles. |
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| Keywords: | Beckmann rearrangement Oxime Dehydration Chlorosulfonic acid Catalysis |
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