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A new method for the synthesis of CF3-containing aminovinyl ketones
Authors:Krasovsky  A. L.  Nenajdenko  V. G.  Balenkova  E. S.
Affiliation:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation
Abstract:A new method for the synthesis of aminovinyl trifluoromethyl ketones was developed. The method is based on the reactions of 4-sulfonyl-1,1,1-trifluorobut-3-ene-2,2-diols with various alkyl-, aryl-, dialkyl-, and alkylarylamines. The stereochemistry of the compounds obtained was studied.
Keywords:  /content/g665080j36581567/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >-sulfonylvinyl(trifluoromethyl)methanediols  amines    /content/g665080j36581567/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >-trifluoroacetylvinylamines  enamines  stereochemistry  nucleophilic substitution
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