Synthesis of biindolyls via palladium-catalyzed reactions |
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| Authors: | Duong Hung A Chua Sheena Huleatt Paul B Chai Christina L L |
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| Affiliation: | Institute of Chemical and Engineering Sciences, Agency for Science, Technology and Research, 1 Pesek Rd, Jurong Island, Singapore 627833. |
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| Abstract: | An unprecedented synthesis of a range of high value homo- and heterobiindolyls is presented. The one-pot Miyaura borylation and subsequent Suzuki-Miyaura coupling sequence allows for the construction of the highly sterically congested C-C bond between two bromoindoles in modest to good overall yields. |
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