| Synthesis and Crystal Structure of Unprecedented Pentanuclear Cu_5~Ⅱ Complex Containing both Macrocyclic and Azido Ligands |
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| 作者单位： | SUN Ya-qiu(Tianjin Key Laboratory of Structure and Performance for Functional Molecule;Tianjin Key Laboratory of Cyto-Genetical and Molecular Regulation, College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300387, P. R. China);FAN Lan-lan,GAO Dong-zhao(Tianjin Key Laboratory of Structure and Performance for Functional Molecule);LIAO Dai-zheng(Department of Chemistry, Nankai University, Tianjin 300071, P. R. China) |
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| 基金项目： | Supported by the National Natural Science Foundation of China(No.20771083) |
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| 摘 要： | ![]()
The organic-inorganic hybrid complex with formula [(CuL)2Cu3(μ-1,1-N3)4(ClO4)2],complex 1,{CuL,[5,6:14,15-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,13-diene-2,3-dione(2-)]copper(II)},has been synthesized and structurally determined. The crystals of complex 1 crystallize in the triclinic system with space group P1,a=0.92983(12) nm,b=1.09644(14) nm,c=1.27396(16) nm,α=70.782(2)°,β=86.266(2)°,γ=78.284(2)°. In this com-plex,the five copper ions are bridged by macrocyclic oxamide groups and azido. Furthermore,C―H...
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| 关 键 词： | 晶体结构 叠氮基 合成 环和 氢键相互作用 超分子结构 有机无机 结构测定 |
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