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Stereospecific synthesis of aryltetraline lignan analogues using 1,6-bis(dipropylboryl)hexa-2,4-diene
Institution:1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, 105118 Moscow, Russian Federation
Abstract:A novel convenient two-stage synthesis of aryltetraline lignin analogues from aromatic aldehydes and diallyl diboron derivatives on the basis of intramolecular Friedel–Crafts reaction has been developed.
Keywords:allylboration  lignan analogues  Friedel–Crafts reaction  benzylic alcohols  organoboron compounds
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