Amphicatalytic polymerization: synthesis of stereomultiblock poly(methyl methacrylate) with diastereospecific ion pairs |
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| Authors: | Chen Eugene Y-X Cooney Megan J |
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| Affiliation: | Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA. eychen@lamar.colostate.edu |
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| Abstract: | ![]()
Diastereospecific ion pairs consisting of isospecific transition-metal cations and syndiospecific main-group anions promote what is termed amphicatalytic polymerization of MMA, producing PMMA with isotactic-b-syndiotactic stereomultiblock microstructures. |
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