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Semiclassical theory of optical rotation. Application of a closed form solution of the optical activity problem
Authors:W.R. Salzman
Affiliation:Department of Chemistry, The University of Arizona, Tucson, Arizona 85721, USA
Abstract:
A previously derived closed form solution to the problem of an atom interacting with an externally supplied classical circularly-polarized electromagnetic field is extended to the case of a freely rotating molecule. It is shown how the conventional Rosenfeld expression for the optical rotation parameter may be derived from the present formalism.
Keywords:
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