Photochemical and thermal rearrangements of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones |
| |
| Authors: | I. Ya. Mainagashev L. S. Klimenko N. P. Gritsan |
| |
| Affiliation: | (1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation;(2) Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090 Novosibirsk, Russian Federation |
| |
| Abstract: | Photochemical transformations of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones involve migration of thetert-butylphenyl group either to theperi-located carbonyl oxygen to give 2-arylamino-9-(4-tert-butylphenoxy)-1,10-anthraquinones or to the nitrogen atom to give 2-aryl(4-tert-butylphenyl)amino-1-hydroxy-9,10-anthraquinones (typical products of the Smiles rearrangement). Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2519–2522, December, 1998. |
| |
| Keywords: | photochemistry Smiles rearrangement 1-(4-tert-butylphenoxy)-2-(p-toluidino)-9,10-anthraquinone 2-(p-anisidino)-1-(4-tert-butylphenoxy)-9,10-anthraquinone |
| 本文献已被 SpringerLink 等数据库收录！ |
|
