| Abstract: | ![]()
Cationic polymerizations of α-methylstyrene and styrene were carried out in an electric field with iodine as a catalyst and ethylene dichloride as the solvent. The effects of the field on the rate of polymerization and the degree of polymerization were studied. It was found that the field increased the rate of polymerization of α-methylstyrene and, also slightly increased the degree of polymerization, whereas the field had no influence on these quantities in the case of styrene. The expressions for the rate of polymerization and the degree of polymerization, which were derived in a previous paper and refined in the present paper, show that these quantities are generally a function of the degree of dissociation of ion pairs at growing chain ends. For a comparatively large degree of dissociation, these expressions can account for the field effect as was observed on α-methylstyrene, if one assumes that the degree of dissociation in the presence of an electric field is larger than that in its absence, and that the free-ion propagation proceeds much faster than the ion-pair propagation. For a small degree of dissociation, however, these expressions become practically independent of the degree of dissociation so that a possible increase due to the presence of an electric field gives rise to no observable effect on the polymerization. This situation may be interpreted as corresponding to the case of styrene. In other words, the polymerization of α-methylstyrene has more free ionic character than that of styrene. |
