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Phase formation in the V2O5-Ta2O5-MoO3 system
Authors:M. G. Zuev
Affiliation:1.Ural State Technical University,Yekaterinburg,Russia;2.Institute of Solid-State Chemistry, Ural Division,Russian Academy of Sciences,Yekaterinburg,Russia
Abstract:Solid-phase interactions in the V2O5-Ta2O5-MoO3 system were studied. The formation of com- pounds TaVO5 and VTa9O25 in the V2O5-Ta2O5 binary system was verified. Tetragonal VTa9O25-base solid solutions of the general formula Ta5 + 4x V5 − 4x O25 (x = 0.25–1) and TaVO5-base solid solutions of the general formula Ta x Mo1 − x V2 − x O8 − 3x (x = 0.625–1) were found to form. Subsolidus phase equilibria in the V2O5-Ta2O5-MoO3 were determined.
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