| β-烷氧羰基乙基三氯化锡与单齿配体配合物的合成及酯交换反应 |
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| 引用本文： | 田来进,傅芳信,朱东升,潘华德.β-烷氧羰基乙基三氯化锡与单齿配体配合物的合成及酯交换反应[J].有机化学,1998,18(1):37-42. |
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| 作者姓名： | 田来进 傅芳信 朱东升 潘华德 |
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| 作者单位： | 曲阜师范大学化学系，东北师范大学化学系，东北师范大学化学系，东北师范大学化学系 曲阜 273165，长春 130024，长春 130024，长春 130024 |
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| 摘 要： | 合成了16个β-烷氧羰基乙基三氯化锡与二甲基亚砜、N-氧化吡啶、吡啶等单齿配体的配合物，经过元素分析、IR、^1H NMR、TG-DTA等表征了其结构。报道了β-烷氧羰基乙基三氯化锡配合物和醇的酯交换反应，提出了其可能的反应机理。
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| 关 键 词： | 吡啶 P 反应机理 羰基络合物 交换反应 有机合成 氯化锡 酯交换 锡络合物 有机锡化合物 烷氧羰基 |
Synthesis and transesterification of the complexes of β- alkoxycarbonylethyltin trichlorides with monodentate ligands |
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| TIAN Lai-Jin.Synthesis and transesterification of the complexes of β- alkoxycarbonylethyltin trichlorides with monodentate ligands[J].Chinese Journal of Organic Chemistry,1998,18(1):37-42. |
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| Authors: | TIAN Lai-Jin |
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| Abstract: | Sixteen complexes of β-alkoxycarbonylethyltintrichlorides with monodentate ligands such as dimethylsulfoxide, pyridine N-oxide and pyridine were synthesized and characterized by elemental analysis, IR, ^1H NMR and TG-DTA. The transesterification of β- methoxycarbonylethyltin trichloride complexes with an alcohol was reported and the possible mechanism was suggested. |
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| Keywords: | PYRIDINE P REACTION MECHANISM CARBONYL COMPLEX EXCHANGE REACTION ORGANIC SYNTHESIS TIN CHLORIDE TRANSESTERIFICATION TIN COMPLEX ORGANO TIN COMPOUNDS ALKOXYCARBONYL GROUP |
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