Diisopropyl-N,N-diethylcarbamylphosphonate complexes with lanthanide nitrates and chlorides
Affiliation:
1. Department of Civil and Environmental Engineering, Wayne State University, 5050 Anthony Wayne Dr., Detroit, MI 48202, USA;2. Department of Civil and Environmental Engineering, University of California at Los Angeles, 420 Westwood Plaza, 5732-Boeelter Hall, Los Angeles, CA 90095, USA;3. Department of Chemistry, Wayne State University, 5101 Cass Ave., Detroit, MI 48202, USA;1. Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, MI, 48202, USA;2. Department of Civil and Environmental Engineering, 5050 Anthony Wayne Drive, Wayne State University, Detroit, MI, 48202, USA
Abstract:
Solid adducts of lanthanide nitrates and chlorides with diisopropyl-N,N-diethylcarbamylphosphonate were prepared and studied. The La, Ce, Pr, Nd, Sm, Gd, and Tb nitrate adducts were isolated and shown to have the structure The Dy, Er, Ho, and Yb nitrate adducts were difficult to isolate and were found to have no single, discrete structure. The chloride adducts of La, Pr, Sm, and Tb were isolated and assigned the structure
