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Catalytic monosilylation of 1,2-diols
Authors:Tsubasa TakeichiMasami Kuriyama  Osamu Onomura
Affiliation:Graduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan
Abstract:
The selective monosilylation of 1,2-diols catalyzed by dimethyltin dichloride was successfully developed. This procedure was applied to various 1,2-diols, giving monosilylated products in good to excellent yields with high chemoselectivity.
Keywords:Dimethyltin dichloride   1,2-Diols   Silylation   Chemoselectivity
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