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Copper‐Catalyzed Heteroarylboration of 1,3‐Dienes with 3‐Bromopyridines: A cine Substitution
Authors:Kevin B. Smith  Dr. Yuan Huang  Prof. M. Kevin Brown
Affiliation:Department of Chemistry, Indiana University, Bloomington, IN, USA
Abstract:
A method for the heteroarylboration of 1,3‐dienes is presented. The process involves an unusual cine substitution of 3‐bromopyridine derivatives to deliver highly functionalized heterocyclic products. Mechanistic studies are included that clarify the details of this unusual process.
Keywords:boron  copper  dienes  heterocycles  synthetic methods
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