| 两个Menschutkin反应溶剂效应的比较 |
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| 引用本文： | 金松寿,胡科诚,俞洁勤,吕克绍,梁恩明,杨晓东.两个Menschutkin反应溶剂效应的比较[J].高等学校化学学报,1987,8(8):743. |
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| 作者姓名： | 金松寿 胡科诚 俞洁勤 吕克绍 梁恩明 杨晓东 |
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| 作者单位： | 杭州大学化学系 |
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| 摘 要： | Menschutkin反应是研究得较多的亲核取代反应之一,对溶剂的动力学效应也进行了广泛和深入的研究,并获得了巨大的成功,但因溶剂对反应速率的影响因素众多,且又错综复杂。
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| 收稿时间： | 1986-03-08 |
The Solvent Effect on Two Menschutkin's Reactions |
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| Jin Songshou,Hu Kecheng,Yu Jieqin,Lu Keshao,Liang Enming,Yang Xjaodong.The Solvent Effect on Two Menschutkin's Reactions[J].Chemical Research In Chinese Universities,1987,8(8):743. |
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| Authors: | Jin Songshou Hu Kecheng Yu Jieqin Lu Keshao Liang Enming Yang Xjaodong |
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| Institution: | Department of Chemistry, Hangzhou University, Hangzhou |
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| Abstract: | The effects of methanol, ethanol, acetone, nitromathane, dimethylformamide, dimethyl sulfoxide and other above twenty solvents upon the rates for two Mens-chutkin's reactions of triethylamine and benzyl chloride, pyridine and benzyl chloride have been investigated. The data obtained show that the solvation seems to have bearing the interaction between characteristic groups on the reaCtant molecules and those on solvent molecules. |
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