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Uranyl complexes with methyl derivatives of alicyclic dioximes
Authors:A G Beirakhov  I M Orlova  E G Il’in  A S Kanishcheva  A V Churakov  Yu N Mikhailov
Institution:1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
Abstract:A reaction of uranyl dioxalate complexes with methyl derivatives of alicyclic ??-dioximes, 3-methyl-1,2-cyclohexanedione dioxime and 3-methyl-1,2-cyclopentanedione dioxime, was studied. The structure of (CN3H6)4(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2O and NH4(CN3H6)3(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2O based on binuclear complex anions with carbonate-dioximate fragment was studied by X-ray diffraction.
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