An Efficient Method for Chemoselective Reduction of Nitro Compounds Using Bimetallic Fe‐Ni NPs/H3PW12O40.×H2O System |
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| Authors: | Soodabeh Rezazadeh Batool Akhlaghinia Elaheh K Goharshadi Hossein Sarvari |
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| Institution: | Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran |
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| Abstract: | The selective reduction of nitro compounds by treatment with bimetallic Fe‐Ni nanoparticles (NPs) and tungestophosphoric acid hydrate (H3PW12O40.×H2O) in H2O is reported. The method has been applied to a broad range of nitro compounds with different sensitive functionalities, including halides, carbonyl, hydroxyl, aldehyde, methyl, acetyl, nitrile, and ester substituents with excellent yields. The reaction yielded single product in all cases with very high yield. The simple experimental procedure and easy purification make the protocol advantageous. |
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| Keywords: | Amines Bimetallic Fe‐Ni NPs Chemoselective reduction |
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