Cyclopentadienyl-silsesquioxane titanium complexes: highly active catalysts for epoxidation of alkenes with aqueous hydrogen peroxide |
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Authors: | Ventura María Mosquera Marta E G Cuenca Tomás Royo Beatriz Jiménez Gerardo |
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Affiliation: | Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain. |
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Abstract: | Titanium complexes bearing an unprecedented tridentate cyclopentadienyl-silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions. |
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