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Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet
Authors:Blagg Robin J  Tuna Floriana  McInnes Eric J L  Winpenny Richard E P
Affiliation:The Lewis Magnetism Laboratory, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Abstract:
Pentametallic Ln complexes of formula [Ln(5)O(O(i)Pr)(13)] have been made, where Ln(III) = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.
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