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Influence of fluoride on f-f transitions of Eu in LiEuM2O8 (M=Mo, W)
Authors:Jiaguo Wang  Xiping Jing  Chunhua Yan  Fuhui Liao
Institution:a College of Chemistry and Materials Science, Wenzhou University, Wenzhou 325027, PR China
b The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
Abstract:The influence of fluoride on the luminescence of LiEuM2O8 (M=Mo, W) was studied. LiEuMo2O8 and LiEuW2O8 formed the whole range of solid solutions, which emitted intense red luminescence under the excitations by 395, 465 and 535 nm wavelengths. When doped with fluoride, the materials also formed solid solutions and the luminescent intensity was remarkably enhanced. The phosphor with optimized compositions in this system would be a promising red component for solid-state lighting devices based on GaN light-emitting diodes.
Keywords:Luminescence  Molybdate  Tungstate  Fluoride  Solid-state lighting
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