Librational model for the direct spin—lattice relaxation process in isolated triplet molecules in a naphthalene-mixed crystal |
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Authors: | F. Dietz U. Konzelmann H. Port M. Schwoerer |
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Affiliation: | Physikalisches Institut, Teil 3, Universität Stuttgart, Stuttgart, Germany;Physikalisches Institut, Universität Bayreuth, Bayreuth, Germany |
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Abstract: | For the spin-lattice relaxation (SLR) in molecular crystals a model is presented, which attributes the SLR mechanism to phonon-stimulated molecular librations. Its applicability to the direct process is shown by comparison with the experimental data on quinoxaline guest molecules in a perdeuterated napthalene host crystal. |
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