On the flash photolysis of phenol derivatives in neutral aqueous solutions: effect of nitrous oxide and alcohols on transients |
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Authors: | Marie-Paule Pileni |
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Institution: | Laboratoire de Biophysique, Muséum National d''Histoire Naturelle, 75005 Paris, France |
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Abstract: | Flash photolysis of N2O saturated neutral aqueous solution of tyrosine phenol and p-cresol leads to OH adduct formation. This species subsequently undergoes either unimolecular water elimination to form the phenoxyl radical or bimolecular radical-radical recombination. Alcohol addition to neutral aqueous solutions provokes the formation of hydrogen atom adduct. |
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