Vibrational spectroscopic study on the phase transition of water in nanospaces and at interfaces

Phase transition of water confined in nanospaces with charged inner-surfaces was investigated by vibrational spectroscopy. Aerosol sodium bis(2-ethylhexyl) sulfosuccinate (AOT) reverse micelles give a series of spherical nanospaces with controlled inner-radius (R_w) with nanometer-scale precision. Successive spectroscopic measurements of the confined water with decreasing temperature revealed that the water freezes to metastable cubic ice (I_c) coexisting with super-cooled water or unstable amorphous ice at the R_w ranging from 1.0 to 2.0 nm. When R_w exceeded 2.0 nm, stable hexagonal ice (I_h) dominated. The drastic change of the dominant ice structure with the increase of 1 nm in R_w shows that the thickness of water layers affected by the inner surface can be estimated to be ~1 nm, where three or four layers of water hydrated to the surface. It is worth noting that the clear phase transition behavior of the confined water vanishes at R_w = 1.2 nm and that the gradual formation of I_c and coexistence of super-cooled water or glassy state of water are detected. The range of the effective interaction between interfacial water and the charged inner surfaces and the mechanism of the extremely slow phase transition were also discussed.