Synthesis and transformations of metallacycles. 23. Cp2TiCl2-Catalyzed cyclometallation of fullerene C60 with EtAlCl2期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Synthesis and transformations of metallacycles. 23. Cp2TiCl2-Catalyzed cyclometallation of fullerene C60 with EtAlCl2

Authors:	Dzhemilev U M Ibragimov A G Khafizova L O Khalilov L M Vasil"ev Yu V Tomilov Yu V

Institution:	(1) Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation;(2) Institute of Physics of Molecules and Crystals, Ufa Research Center of the Russian Academy of Sciences, 6 ul. Karla Marksa, 450000 Ufa, Russian Federation;(3) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

Abstract:	1-Ethyl-2,3-fullerenoaluminacyclopropanes (EtAl)_n(²-C₆₀) were synthesized by the reaction of fullerene C₆₀ with an excess of EtAlCl₂ in the presence of Mg and using Cp₂TiCl₂ as the catalyst in a THF--toluene solution at 20 °C. Deuterolysis of fullerenoaluminacyclopropanes afforded a mixture of deuteriofullerenes C₆₀D_m, where m = 6--12.

Keywords:	catalysis organoaluminum compounds fullerenes cyclometallation hydrolysis deuterolysis
本文献已被 SpringerLink 等数据库收录！