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SYNTHESIS OF HIGH MOLECULAR WEIGHT POLY(p-PHENYLENE SULFIDE) RESINS
Authors:Jixing Luo  Yunsong Yang  Hao Li  Ze Zhao  Jige Song
Affiliation:Department of Chemistry, Sichuan University Chengdu, Sichuan 610064
Abstract:This is a method of producing crystal linear high molecular weight poly p-phenylene sulfide (HMWPPS) resins by mixing hydrogen sulfide which is produced from the acid gas of desulphurization factory of natural gas, sodium hydroxide, p-dichlorobenzene and additive sodium phosphate, and carrying out the polycondensation in hexamethyl phosphoryl triamide (HPTA) solvent for 4 to 6 h under normal pressure. This method has obvious advantages as simple equipment, easy operation, high activity, stable solvent, high product yield, low cost and it is suitable for large-scale industrial production.
Keywords:high molecular weight poly( p phenylene sulfide)  recurring unit  shearing viscosity  hexamethyl phosphoryl triamide
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