Total synthesis and absolute configuration determination of (+)-subincanadine F |
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| Authors: | Chen Pinhong Cao Lidong Tian Wenhai Wang Xinfeng Li Chaozhong |
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| Institution: | Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, PR China. |
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| Abstract: | The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned. |
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