Thermal and chromatographic behaviour of metal complexes. Part III. Complexes of palladium(II) with iminodiacetic acid |
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| Authors: | M.Castillo Martos F.Gonzalez Vilchez E.Ramirez Carrasco |
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| Affiliation: | Departamento de Química Inorgánica, Facultad de Química, Universidad de Sevilla, Sevilla Spain |
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| Abstract: | A study of the thermal properties of the complexes formed between Pd(II) and iminodiacetic acid (IDA) and the chromatographic analysis of their thermal decomposition products have been carried out. The dehydration of the isolated compounds is detected above 100°C. The decarboxylation process of the COO? groups takes place yielding CO2 and CO simultaneously or consecutively if they are not coordinated, respectively. The formation of gases (methane, ethane, etc.) is also observed. |
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| Keywords: | To whom correspondence should be addressed. |
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