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Quantitative determination of interfacial adhesion in composites with strong bonding |
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| Authors: | Károly Renner János Móczó György Vörös Béla Pukánszky |
| Institution: | a Laboratory of Plastics and Rubber Technology, Budapest University of Technology and Economics, P.O. Box 91, H-1521 Budapest, Hungary b Institute of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary c Department of Materials Physics, Eötvös University Budapest, P.O. Box 32, H-1518 Budapest, Hungary |
| Abstract: | An approach was proposed for the quantitative determination of adhesion strength in composites, in which adhesion is created by other mechanisms than secondary interactions. The approach is based upon a model, which gives debonding stress as a function of interfacial adhesion. Debonding stress was determined by acoustic emission experiments. The mechanism of deformation was checked by SEM experiments and the approach was verified on composites with known interfacial adhesion. The results showed that the use of functionalized polymer in PP/CaCO3 composites resulted in adhesion strength one order of magnitude larger than without the coupling agent. The application of various surface modification techniques in PP/glass bead composites yielded different adhesion values covering a range of about one order of magnitude. The quantitative determination of interfacial adhesion makes possible the design and optimization of most surface modification techniques in particulate filled and short fiber reinforced composites. |
| Keywords: | Composites Poly(propylene) (PP) Acoustic emission Debonding Adhesion |
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