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Advanced high-performance liquid chromatography method for highly polar nitroaromatic compounds in ground water samples from ammunition waste sites |
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| Authors: | A. Preiss A. Bauer H.-M. Berstermann S. Gerling R. Haas A. Joos A. Lehmann L. Schmalz K. Steinbach |
| Affiliation: | 1. Fraunhofer-Institut für Toxikologie und Experimentelle Medizin (ITEM), Nikolai-Fuchs-Strasse 1, 30625 Hannover, Germany;2. Fraunhofer-Institut für Molekularbiologie und Angewandte Ökotoxikologie (IME), 57392 Schmallenberg, Germany;3. Wartig Chemieberatung GmbH, Rudolf-Breitscheid-Strasse 24, 35037 Marburg, Germany;4. Büro für Altlastenerkundung und Umweltforschung, Stadtwaldstrasse 45a, 35037 Marburg, Germany;5. IABG, Alt-Moabit 94, 10559 Berlin, Germany;6. Bundesanstalt für Materialforschung und –prüfung (BAM), Richard-Willstätter-Strasse 11, 12489 Berlin, Germany;g Dresdner Grundwasserforschungszentrum e.V., Meraner Strasse 10, 01217 Dresden, Germany;h Philipps-Universität, Department of Chemistry, Hans-Meerwein-Strasse, 35032 Marburg, Germany |
| Abstract: | An advanced HPLC-photodiode array detection method for the determination of 12 selected highly polar nitroaromatic compounds in ground water samples of ammunition waste sites has been developed and validated. After solid-phase extraction the limits of detection were in the range 0.1–0.5 μg/l. To prove the applicability of the method to other polar nitroaromatic compounds the retention time of another 32 polar compounds under the specified chromatographic conditions were determined and their UV spectra recorded. To review the method, interlaboratory comparisons were performed with a spiked and a real ground water sample. |
| Keywords: | HPLC-photodiode array detection method Highly polar nitroaromatic compounds Ammunition waste sites Interlaboratory tests |
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