| 光诱导钌配合物的几何异构和结构异构反应研究进展 |
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| 引用本文： | 靳晓伟,王建茹,段青青,乔晓艳,王宏飞.光诱导钌配合物的几何异构和结构异构反应研究进展[J].影像科学与光化学,2012,30(6):401-410. |
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| 作者姓名： | 靳晓伟 王建茹 段青青 乔晓艳 王宏飞 |
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| 作者单位： | 1. 山西大学 物理电子工程学院, 山西 太原 030006;2. 山西大学 光电研究所, 山西 太原 030006 |
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| 基金项目： | 山西省回国留学人员科研资助项目 |
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| 摘 要： | 金属钌(Ru)的配合物具有丰富的基态和激发态的光物理、光化学性质,在太阳能转换、光催化以及分子识别等方面都得到了广泛深入的研究.光诱导的钌配合物的异构反应是其颇具特色的一类光反应,研究光异构反应对于光能量转化、信息储存以及"分子光开关"和"分子马达"的设计具有重要的意义.本文小结和综述了钌配合物的光诱导几何异构和结构异构反应的特性和机理以及最新的研究进展.
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| 关 键 词： | 钌配合物 光反应 几何异构 结构异构 激发态 亚稳态 |
| 收稿时间： | 2012-05-10 |
Photo-Induced Isomerization Reaction of Ruthenium Complexes |
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| JIN Xiao-wei
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WANG Jian-ru
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DUAN Qing-qing
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QIAO Xiao-yan
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WANG Hong-fei.Photo-Induced Isomerization Reaction of Ruthenium Complexes[J].Imaging Science and Photochemistry,2012,30(6):401-410. |
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| Authors: | JIN Xiao-wei WANG Jian-ru DUAN Qing-qing QIAO Xiao-yan WANG Hong-fei |
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| Institution: | 1. College of Physics & Electronics Engineering, Shanxi University, Taiyuan 030006, Shanxi, P.R. China;2. Institute of Opto-Electronics, Shanxi University, Taiyuan 030006, Shanxi, P.R. China |
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| Abstract: | Ruthenium(Ru) complex,are among the most investigated in fields that include solar energy conversion,photocatalysis and molecular recognition,owing to their favorable photophysical and photochemical properties as well as ground state and excited state reactivity.The photo-induced isomerization is one kind of novel reactions for ruthenium complexes,and the study for photo isomerization is of great significance for the light energy conversion,information storage,as well as the design for "molecular switch" and "molecular motor".Herein,the different types,characteristics and mechanism of photo-induced isomerization of ruthenium complexes as well as the recent progress were reviewed. |
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| Keywords: | ruthenium complexes photo reaction geometric isomerism structural isomerism excited state metastable state |
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