Enhancement of the catalytic activity of [Cu2(TS)(OH)2(OAc)] using superconductor cuprate sample |
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Authors: | Maany M Hamada Ola El-Shafai Ahmed A El-Asmy |
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Institution: | (1) Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt |
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Abstract: | A superconducting sample (Nd0.1Y0.9Ba2Cu3O7-δ) has been tried as a catalyst for H2O2 decomposition. All parameters affecting the reaction rate (concentration of H2O2, weight of catalyst, temperature and pH) were studied and the optimum conditions were evaluated. A mixture of the superconducting
cuprate with Cu2(TS)(OH)(OAc)] using different percentages of the sample has been prepared and tried kinetically under the same mentioned
conditions. An attempt was made to increase the activity of the complex. The data show that the cuprate sample alone was found
to be almost inactive when compared with that of the mixture. The catalytic mechanism in the absence and presence of the complex
was suggested. |
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Keywords: | |
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