Anomalous surface enhanced molecular Raman scattering from inelastic tunneling spectroscopy junctions

Anomalously strong Raman spectra have been obtained from molecular monolayers adsorbed on the insulator in metal-insulator-metal tunnel junctions. We show unambiguously that Raman spectroscopy can readily detect molecular monolayers and consider the effects of surface roughness, the molecule-metal interface and the metal on our results.