Preparation and characterization of bis(acetonitrile)bis(acetylacetonato)technetium(III) |
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Authors: | A Mutalib T Omori K Yoshihara |
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Institution: | (1) Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku, 980 Sendai, Japan;(2) Department of Chemistry, Faculty of Science, Shizuoka University, 422 Ohtani, Shizuoka, Japan |
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Abstract: | A new chemical species of bis(acetonitrile)bis(acetylacetonato)technetium(III), Tc(acac)2(CH3CN)2]+, has been prepared by the reaction of tris(acetylacetonato)technetium(III) with acetonitrile in the presence of a strong acid, perchloric or hydrochloric acid. The reaction kinetics were followed by observing spectral change of Tc(acac)3 in the UV-visible region. The complex has been characterized by combination of elemental analyses, IR and UV-visible spectrophotometry, ion-exchange chromatography, and paper electrophoresis. Applicability of this substance to synthesize mixed-ligand technetium(III) complexes was discussed based on the solubility of this complex and the ease of substitution of the acetonitrile ligand. |
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