Aziridines as a protecting and directing group. Stereoselective synthesis of (+)-bromoxone |
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| Authors: | Barros M Teresa Matias Pedro M Maycock Christopher D Ventura M Rita |
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| Institution: | Departamento de Química, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, 2825 Monte da Caparica, Portugal. |
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| Abstract: | reaction: see text] The directing ability of an aziridine group for the epoxidation of adjacent double bonds is demonstrated. The aziridine group is also used to effectively protect a double bond in a cycloenone system for a short synthesis of the title compound. |
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