New catalytic route to borasiloxanes |
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| Authors: | Marciniec Bogdan Walkowiak Jedrzej |
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| Affiliation: | Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland. marcinb@amu.edu.pl |
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| Abstract: | ![]()
A new, highly selective method for effective synthesis of boryl silyl ethers (borasiloxanes) via O-borylation of silanols with vinylboronates catalyzed by the Ru-H complexes [RuHCl(CO)(PCy3)2] and [RuHCl(CO)(PPh3)3] is described. |
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