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Intercrosslinked polymer networks by simultaneous curing of unsaturated polyesters and bismaleimide resins
Authors:M. Abbate  V. Di Liello  E. Martuscelli  P. Musto  G. Ragosta  G. Scarinzi
Abstract:The modification of an unsaturated polyester resin by incorporating a second co-reactive monomer as a thermosetting bismaleimide is described The bismaleimide was readily dissolved in the uncured polyester matrix up to a concentration of about 20% wt. FTIR isothermal measurements indicated that the kinetics and the mechanism of the curing process were strongly affected by the presence of the bismaleimide. The resulting inter-crosslinked network showed a gradual enhancement of the elastic modulus in a wide range of temperatures by increasing the bimaleimide amount in the system. This enhancement was obtained without altering the intrinsic toughness of the matrix.
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