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Ethyl and isopropyl 4‐ferrocenylbenzoate
Authors:Frankie P. Anderson  John F. Gallagher  Peter T. M. Kenny  Clodagh Ryan  David Savage
Abstract:
The title compounds, [Fe(C5H5)(C14H13O2)] and [Fe(C5H5)(C15H15O2)], respectively, contain the ferrocenyl η5(C5H4) and phenyl­ene –C6H4– rings in a nearly coplanar arrangement, with interplanar angles of 6.88 (12) and 10.5 (2)°, respectively. Molecules of the ethyl ester form dimers through η5(C5H5)C—H⋯O=C hydrogen bonds, with graph set R(20), and, together with Csp3—H⋯π(C5H5) interactions, generate a one‐dimensional column (irregular ladder). Molecules of the iso­propyl ester aggregate through η5(C5H5)C—H⋯π(C6H4) interactions.
Keywords:
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