A ruthenium complex with 1,5‐diphenyl‐3‐thiocarbazone (dithizone) as monodentate ligands: bis(2,2′‐bipyridyl‐κ2N,N′)bis(dithizonato‐κS)ruthenium(II)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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A ruthenium complex with 1,5‐diphenyl‐3‐thiocarbazone (dithizone) as monodentate ligands: bis(2,2′‐bipyridyl‐κ2N,N′)bis(dithizonato‐κS)ruthenium(II)

Authors:	Gary L Seamans Jerry L Walsh Mariusz Krawiec William T Pennington

Abstract:	The title compound, Ru(C₁₃H₁₁N₄S)₂(C₁₅H₈N₂)₂], has C₂ symmetry, with bidentate 2,2′‐bipyridyl ligands dictating a cis geometry around the Ru^II center. The monodentate S‐bonded dithizone ligands are almost planar, except for one of the phenyl rings, which is twisted by 34.2 (4)° from the N/N/C(S)/N/N plane. The Ru—S bond length is 2.4140 (13) Å, and the Ru—N bond lengths are 2.048 (4) and 2.074 (4) Å.

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