cis‐[1,4‐Bis(diphenylphosphino)butane](μ‐tetrathiotungstato)palladium(II) N,N′‐dimethylformamide hemisolvate hemihydrate |
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Authors: | Kai Liang Yi‐Zhi Li He‐Gen Zheng Xin‐Quan Xin |
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Abstract: | In the title compound, 1,4‐bis(diphenylphosphino)butane‐2κ2P,P′]di‐μ‐thio‐1:2κ4S‐dithio‐1κ2S‐palladium(II)tungsten(VI) N,N′‐dimethylformamide hemisolvate hemihydrate, PdWS4(C28H28P2)]·0.5C3H7NO·0.5H2O, the Pd atom is coordinated by two S atoms from the distorted‐tetrahedral WS4]2? anion and two P atoms from the dppb molecule dppb is 1,4‐bis(diphenylphosphino)butane] in an approximately square‐planar configuration. A puckered seven‐membered ring is formed by the Pd atom and the dppb ligand. |
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