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cis‐[1,4‐Bis(di­phenyl­phosphino)­butane](μ‐tetra­thio­tungstato)­palladium(II) N,N′‐di­methyl­form­amide hemisolvate hemihydrate
Authors:Kai Liang  Yi‐Zhi Li  He‐Gen Zheng  Xin‐Quan Xin
Abstract:In the title compound, 1,4‐bis(di­phenyl­phosphino)­butane‐2κ2P,P′]­di‐μ‐thio‐1:2κ4S‐di­thio‐1κ2S‐palladium(II)­tung­sten(VI) N,N′‐di­methyl­form­amide hemisolvate hemihydrate, PdWS4­(C28H28P2)]·0.5C3H7NO·0.5H2O, the Pd atom is coordinated by two S atoms from the distorted‐tetrahedral WS4]2? anion and two P atoms from the dppb mol­ecule dppb is 1,4‐bis(di­phenyl­phos­phino)­butane] in an approximately square‐planar configuration. A puckered seven‐membered ring is formed by the Pd atom and the dppb ligand.
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